fermentation final electron acceptor
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- X + eâˆ’â†’ Xâˆ’
The electron affinity, Eea, is defined as positive when the resulting ion has a lower energy, i.e. it is an exothermic process that releases energy:
- Eea = Einitial âˆ’ Efinal
- Xâˆ’â†’ X + eâˆ’
Electron affinities of the elements
Although Eea varies greatly across the periodic table, some patterns emerge. Generally, nonmetals have more positive Eea than metals. Atoms whose anions are more stable than neutral atoms have a greater Eea. Chlorine most strongly attracts extra electrons; mercury most weakly attracts an extra electron. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.
Eea generally increases across a period (row) in the periodic table. This is caused by the filling of the valence shell of the atom; a group 7A atom releases more energy than a group 1A atom on gaining an electron because it obtains a filled valence shell and therefore is more stable.
A trend of decreasing Eea going down the groups in the periodic table would be expected. The additional electron will be entering an orbital farther away from the nucleus, and thus would experience a lesser effective nuclear charge. However, a clear counterexample to this trend can be found in group 2A, and this trend only applies to group 1A atoms. Electron affinity follows the trend of electronegativity. Fluorine (F) has a higher electron affinity than oxygen and so on.
The following data are quoted in kJ/mol. Elements marked with an asterisk are expected to have electron affinities close to zero on quantum mechanical grounds. Elements marked with a dotted box are synthetically made elementsâ€”elements not found naturally in the environment.
Molecular electron affinities
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silicoexperiments show that the electron affinity ofhexacyanobenzene surpasses that of fullerene.
Electron affinity of Surfaces
The electron affinity measured from a material's surface is a function of the bulk material as well as the surface condition. Often negative electron affinity is desired to obtain efficient cathodes that can supply electrons to the vacuum with little energy loss. The observed electron yield as a function of various parameters such as bias voltage or illumination conditions can be used to describe these structures with band diagrams in which the electron affinity is one parameter. For one illustration of the apparent effect of surface termination on electron emission, see Figure 3 in Marchywka Effect.
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