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Example of Methods of Separating Mixture

An element is composed of only one kind of atom which cannot be broken down into a simpler type of matter by any physical or chemical method. The combination of two or more atoms of same or different types results the formation of molecule. In a molecule, the atoms are bonded through chemical bonds such as ionic bond or covalent bond. Compounds are composed of atoms of two or more different elements which are bonded together. They can be decomposed into a simpler type of matter with the help of some chemical methods. Compounds show different chemical and physical properties compare to their component elements.

Mixtures are composed of two or more different elements or compounds which are physically intermingled with each other. The components of mixture can be separated into its components by physical methods. The components of mixtures retain their properties in it. On the basis of composition, mixtures can be classified in two types; heterogeneous and homogenous. In a homogenous mixture, components are uniformly combined and distributed evenly throughout the mixture.

On the contrary, in the heterogeneous mixtures the components are not equal throughout and can be easily separated into individual components. For separating the components a mixture, there are several methods which mainly depend on the type of mixture and its ingredients. 

Let’s discuss few methods of separation of components of mixtures Crystallization is one of the most common method for the separation of components of mixture. We can separate many solids from the saturated solutions by leaving them to form crystals. In the saturated solution, the solvent evaporates at high temperature and left behind the crystals of solute. Filtration is another method for separation of mixtures.

In this method, the mixture is poured over an appropriately-sized filter so that the liquid drains into a container underneath and residue remains on the filter paper. On the basis of boiling point of components, mixtures can purify with the use of distillation technique. This method can be used in such case when the difference in the boiling point of both components is too large.  In distillation, the liquid mixture is heated till vaporization. It left the heavier material suspended in the liquid condensed at the bottom of the container and vapour can be removed through a condenser tube. This vapour can be easily condensed into liquid in another container. In the fractional distillation, different liquids boil at different temperatures.

When the mixture is heated, it boils off and condenses at different times.  The apparatus of this process contains a fractionating column in which only the liquid boils at its boiling point and can pass into the condenser. For example this technique can be used to separate the mixture of ethanol and water.

One of the best methods of separation is chromatography which is mainly used to separate different coloured dyes.  There are different types of chromatographic methods such as paper chromatography, thin layer chromatography, gas chromatography and HPLC.  In the paper chromatography, the solution of dyes travels up on the chromatography paper at different distances due to different absorbance power. This technique is used to separate only a small amount of mixture samples. Evaporation method is used to separate a soluble solid from a liquid.  Separating funnel is used to separate two immiscible liquids such as oil and water.

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From Wikipedia

Mixture

In chemistry, a mixture is a material system made up by two or more different substances which are (mixed) together but are not combined chemically. Mixture refers to the physical combination of two or more substances the identities of which are retained. The molecules of two or more different substances are mixed in the form of alloys, solutions, suspensions, and colloids.

Mixtures are the product of a mechanical blending or mixing of chemical substances like elements and compounds, without chemical bonding or other chemical change, so that each ingredient substance retains its own chemical properties and makeup. Nonetheless, despite there are no chemical changes to its constituents, the physical properties of a mixture, such as its melting point, may differ from those of the components. Some mixtures can be separated into their components by physical (mechanical or thermal) means. Azeotropes can be considered as a kind of mixture which usually pose considerable difficulties regarding the separation processes required to obtain their constituents (physical or chemical processes or, even a blend of them).

Mixtures can be either homogeneous or heterogeneous. A homogeneous mixture is a type of mixture in which the composition is uniform. A heterogeneous mixture is a type of mixture in which the composition can easily be identified, as there are two or more phases present. Air is a homogeneous mixture of the gaseous substances nitrogen, oxygen, and smaller amounts of other substances. Salt, sugar, and many other substances dissolve in water to form homogeneous mixtures. A homogeneous mixture in which there is both a solute and solvent present is also a solution.

The following table shows the main properties of the three families of mixtures.

The following table shows examples of the three types of mixtures.

Physics and Chemistry

A heterogeneous mixture is a mixture of two or more compounds. Examples are: mixtures of sand and water or sand and iron filings, a conglomerate rock, water and oil, a salad, trail mix, and concrete (not cement). Gy's sampling theory quantitatively defines the heterogeneity of a particle as:

h_i = \frac{(c_i - c_\text{batch})m_i}{c_\text{batch} m_\text{aver}} .

where h_i, c_i, c_\text{batch}, m_i, and m_\text{aver} are respectively: the heterogeneity of the ith particle of the population, the mass concentration of the property of interest in the ith particle of the population, the mass concentration of the property of interest in the population, the mass of the ith particle in the population, and the average mass of a particle in the population.

During the sampling of heterogeneous mixtures of particles, the variance of the sampling error is generally non-zero.

Pierre Gy derived, from the Poisson sampling model, the following formula for the variance of the sampling error in the mass concentration in a sample:

V = \frac{1}{(\sum_{i=1}^N q_i m_i)^2} \sum_{i=1}^N q_i(1-q_i) m_{i}^{2} \left(a_i - \frac{\sum_{j=1}^N q_j a_j m_j}{\sum_{j=1}^N q_j m_j}\right)^2 .

in which V is the variance of the sampling error, N is the number of particles in the population (before the sample was taken), q i is the probability of including the ith particle of the population in the sample (i.e. the first-order inclusion probability of the ith particle), m i is the mass of the ith particle of the population and a i is the mass concentration of the property of interest in the ith particle of the population.

It must be noted that the above equation for the variance of the sampling error is an approximation based on a linearization of the mass concentration in a sample.

In the theory of Gy, correct sampling is defined as a sampling scenario in which all particles have the same probability of being included in the sample. This implies that q i no longer depends on i, and can therefore be replaced by the symbol q. Gy's equation for the variance of the sampling error becomes:

V = \frac{1-q}{q M_\text{batch}^2} \sum_{i=1}^N m_{i}^{2} \left(a_i - a_\text{batch} \right)^2 .

where abatch is the concentration of the property of interest in the population from which the sample is to be drawn and Mbatch is the mass of the population from which the sample is to be drawn.



From Yahoo Answers

Question:Can you please tell me about : Filtration , Sifting ( using sieves ) , Magnetism , Evaporation , Flotation , Dissolving , && panning . =]

Answers:Filtration uses the method of separating larger particles from smaller particles using a filter (usually of paper). If you have coffee grounds, you can put water through it. Small particles of coffee that dissolve in the water will go through and larger grounds will stay back. Sifting uses a strainer, also using the concept of smaller and larger particles. Magnetism separates objects made of iron and those that are not. If you have iron filings and wood shavings, you can use a magnet to attract all of the filings. Evaporation is used to separate particles that are dissolved in a liquid, like saltwater. If you leave a glass of saltwater in the sun, eventually, all the of the water dries up and all that is left is salt. Flotation works for things that are less dense than another substance, like wood shavings that would float in water. Dissolving works if you have to separate salt and pepper. Salt will dissolve in water which you can then pour through a filter or a fine strainer. Then, you can evaporate the saltwater to give you back salt. Panning works for dense objects like gold from sand like how gold miners find gold. The gold will sink to the bottom of the pan while the lighter sand will easily come out.

Question:please do not write about fractional distillation.

Answers:High-performance liquid chromatography (HPLC) read all about it here: ref: http://en.wikipedia.org/wiki/High_performance_liquid_chromatography

Question:What is an example of a mixture that can be separated by filtration?

Answers:salt..and mixture that have different boiling points

Question:i have a science project that i have to do on separating mixtures in every day life, ex. oil spills from water. i want to do something somewhat original, and i have no ideas! if you guys have any ideas, it would be a big help! thanks!

Answers:well here are some mixtures which are separated in other fields...... In cooking, you normally skim off the oil/fat from the gravy or broth In cooking, you sometimes need to separate the egg yolk from the egg white to make meringues YUM In gas tanks, if water separates out from the gasoline (or too much water is in the gas tank) it will separate out and cause the car starting problems. Why they add gasoline additives in (methanol or ethanol) to prevent this, especially in cold weather. we all separate recyclables for collection (well we should).. consider cooking as a way into a different part of chemistry.:) just a thought

From Youtube

Separation: Iron & Sand Mixture :There are many means of separating mixtures in chemistry. One such method is not very common, but takes advantage of the magnetic properties of iron (and a few other elements) to extract it from mixtures. This clip shows iron being removed from a mixture of iron filings and sand.

Mixtures :Teachzer.com - This video discusses the differences between mixtures and compounds. It also goes through the different methods in separating mixtures into the individual substances.